Heck–Mizoroki coupling of vinyliodide and applications in the synthesis of dienes and trienes1. Issue 57 (21st July 2015)

• Record Type: Journal Article
• Authors: Madden, Katrina S.; David, Sylvain; Knowles, Jonathan P.; Whiting, Andrew
• Is Part Of: Chemical communications. Volume 51:Issue 57(2015)
• Page Start: 11409
• Page End: 11412
• Publication Date: 2015-07-21
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc03273c
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1xv5d3f9" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Vinyliodide reacts chemoselectively under Heck–Mizoroki conditions with terminal alkenes to give diene products, including vinyl boronate esters, and the resulting dienylboronate undergoes Suzuki–Miyaura coupling with aryl, heteroaryl and alkenyl halides to access dienes and trienes.</p> </abstract>