A two‐dimensional ZnII coordination polymer constructed from benzene‐1, 2, 3‐tricarboxylic acid and N, N′‐bis[(pyridin‐4‐yl)methylidene]hydrazine. Issue 7 (12th June 2015)

• Record Type: Journal Article
• Authors: Wang, Xiangfei; Yang, Fang; Tang, Meng; Yuan, Limin; Liu, Wenlong
• Is Part Of: Acta crystallographica. Volume 71:Issue 7(2015:Jul.)
• Page Start: 521
• Page End: 525
• Publication Date: 2015-06-12
• Subjects: Crystallography -- Periodicals; Crystals -- Periodicals; 548.3
• DOI: 10.1107/S2053229615010657
• Languages: English
• ISSNs: 2053-2296

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>The hydrothermal synthesis of the novel complex poly[aqua(μ₄‐benzene‐1, 2, 3‐tricarboxylato)[μ₂‐4, 4′‐(hydrazine‐1, 2‐diylidenedimethanylylidene)dipyridine](μ₃‐hydroxido)dizinc(II)], [Zn(C₉H₃O₆)(OH)(C₁₂H₁₀N₄)(H₂O)]_{<italic>n</italic>}, is described. The benzene‐1, 2, 3‐tricarboxylate ligand connects neighbouring Zn₄(OH)₂ secondary building units (SBUs) producing an infinite one‐dimensional chain. Adjacent one‐dimensional chains are connected by the <italic>N</italic>, <italic>N</italic>′‐bis[(pyridin‐4‐yl)methylidene]hydrazine ligand, forming a two‐dimensional layered structure. Adjacent layers are stacked to generate a three‐dimensional supramolecular architecture <italic>via</italic> O—H...O hydrogen‐bond interactions. The thermal stability of this complex is described and the complex also appears to have potential for application as a luminescent material.</p> </abstract>