Photoelectrochemical CO2 reduction using a Ru(ii)–Re(i) multinuclear metal complex on a p-type semiconducting NiO electrode1. Issue 53 (7th July 2015)

• Record Type: Journal Article
• Authors: Sahara, Go; Abe, Ryu; Higashi, Masanobu; Morikawa, Takeshi; Maeda, Kazuhiko; Ueda, Yutaro; Ishitani, Osamu
• Is Part Of: Chemical communications. Volume 51:Issue 53(2015)
• Page Start: 10722
• Page End: 10725
• Publication Date: 2015-07-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc02403j
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj146s20j2" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A photocathode for CO₂ reduction was developed using a hybrid comprising a Ru(<sc>ii</sc>)–Re(<sc>i</sc>) supramolecular photocatalyst and a NiO electrode. Photoexcitation of the Ru photosensitizer selectively gave CO with high faradaic efficiency.</p> </abstract>