Imido-pyridine Ti(iv) compounds: synthesis of unusual imido–amido heterobimetallic derivatives1. Issue 24 (28th June 2015)

• Record Type: Journal Article
• Authors: Pedrosa, Sergio; Vidal, Fernando; Lee, Lucia Myongwon; Vargas-Baca, Ignacio; Gómez-Sal, Pilar; Mosquera, Marta E. G.
• Is Part Of: Dalton transactions. Volume 44:Issue 24(2015)
• Page Start: 11119
• Page End: 11128
• Publication Date: 2015-06-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt01320h
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1018hztx" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Controlled generation of novel bridging or terminal imido-pyridine complexes is achieved, including the unusual species [Li(THF)][Ti(η⁵-C₅Me₅)(NR)(NHR)₂]. Computational studies corroborate its charge-separated nature.</p> </abstract>