Direct coupling of unactivated alkynes and C(sp3)–H bonds catalyzed by a Pt(ii, iv)-centered catalyst: a computational study1. Issue 40 (7th May 2015)

• Record Type: Journal Article
• Authors: Li, Zhi-Feng; Li, Hui-Xue; Yang, Xiao-Ping; Liu, Xin-Wen; Zuo, Guo-Fang; Zhao, Cunyuan
• Is Part Of: RSC advances. Volume 5:Issue 40(2015)
• Page Start: 31954
• Page End: 31964
• Publication Date: 2015-05-07
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra05458c
• Languages: English
• ISSNs: 2046-2069

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjjksxzxp" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Direct coupling of unactivated alkynes and C(sp³)–H bonds catalyzed by a Pt(<sc>ii</sc>, <sc>iv</sc>)-centered catalyst X (X = PtCl₂, PtBr₂, PtI₂ and PtI₄) (<italic>J. Am. Chem. Soc.</italic> 2009, <bold>131</bold>, 16525) have been theoretically investigated with density functional theory (DFT).</p> </abstract>