Influence of structural and electronic properties of organomolybdenum(ii) complexes of the type [CpMo(CO)3R] and [CpMo(O2)(O)R] (R = Cl, CH3, CF3) on the catalytic olefin epoxidation1. Issue 4 (24th April 2015)

• Record Type: Journal Article
• Authors: Hauser, Simone A.; Reich, Robert M.; Mink, János; Pöthig, Alexander; Cokoja, Mirza; Kühn, Fritz E.
• Is Part Of: Catalysis science & technology. Volume 5:Issue 4(2015:Apr.)
• Page Start: 2282
• Page End: 2289
• Publication Date: 2015-04-24
• Subjects: Catalysis -- Periodicals; 541.395
• DOI: 10.1039/c4cy01604a
• Languages: English
• ISSNs: 2044-4753

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjjh1xwj5" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Six compounds of the type [CpMo(CO)₃R] (R = Cl (<bold>1</bold>), CH₃ (<bold>2</bold>), CF₃ (<bold>3</bold>)) and [CpMo(O₂)(O)R] (R = Cl (<bold>4</bold>), CH₃ (<bold>5</bold>), CF₃ (<bold>6</bold>) (Cp = η⁵-cyclopentadienyl)) have been synthesised and characterised.</p> </abstract>