The origins and mechanism of phase transformation in bulk Li2MnO3: first-principles calculations and experimental studies1. Issue 13 (7th April 2015)

• Record Type: Journal Article
• Authors: Lim, Jin-Myoung; Kim, Duho; Lim, Young-Geun; Park, Min-Sik; Kim, Young-Jun; Cho, Maenghyo; Cho, Kyeongjae
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 13(2015)
• Page Start: 7066
• Page End: 7076
• Publication Date: 2015-04-07
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c5ta00944h
• Languages: English
• ISSNs: 2050-7488

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjjgt4f4h" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Our observations indicate that thermodynamically stable and kinetically movable intermediate tetrahedral states of Mn are the main origin of Mn migration, leading to the phase transformation of Li₂MnO₃.</p> </abstract>