Re-evaluating the Cu K pre-edge XAS transition in complexes with covalent metal–ligand interactions1. Issue 4 (16th April 2015)

• Record Type: Journal Article
• Authors: Tomson, Neil C.; Williams, Kamille D.; Dai, Xuliang; Sproules, Stephen; DeBeer, Serena; Warren, Timothy H.; Wieghardt, Karl
• Is Part Of: Chemical science. Volume 6:Issue 4(2015:Apr.)
• Page Start: 2474
• Page End: 2487
• Publication Date: 2015-04-16
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c4sc03294b
• Languages: English
• ISSNs: 2041-6520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjjgsn5wb" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Covalent metal–ligand interactions can lead to Cu K pre-edge transitions that result from metal-to-ligand charge transfer, instead of 1s → 3d, character.</p> </abstract>