Two types of nitrito support for μ4-oxido-bridged [Cu4] complexes: synthesis, crystal structures, magnetic properties and DFT analysis1. Issue 13 (7th April 2015)

• Record Type: Journal Article
• Authors: Pait, Moumita; Shatruk, Michael; Lengyel, Jeff; Gómez-Coca, Silvia; Bauzá, Antonio; Frontera, Antonio; Bertolasi, Valerio; Ray, Debashis
• Is Part Of: Dalton transactions. Volume 44:Issue 13(2015)
• Page Start: 6107
• Page End: 6117
• Publication Date: 2015-04-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03224a
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjjgsc2np" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> <italic>In situ</italic> generated NO₂⁻ and externally added NO₂⁻ and AcO⁻ ions have been utilized for the isolation of μ₄-oxido-bridged Cu₄ aggregates showing magnetic coupling which can be rationalized by DFT calculations.</p> </abstract>