ChemInform Abstract: A General, Scalable, Organocatalytic Nitro‐Michael Addition to Enones: Enantioselective Access to All‐Carbon Quaternary Stereocenters. Issue 31 (August 2015)

• Record Type: Journal Article
• Authors: Gu, Xiaodong; Dai, Yuanyuan; Guo, Tingting; Franchino, Allegra; Dixon, Darren J.; Ye, Jinxing
• Is Part Of: ChemInform. Volume 46:Issue 31(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-08
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201531029
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A tert‐leucine‐derived chiral diamine efficiently catalyzes the asymmetric Michael addition of nitromethane to five, six‐, and seven‐membered β‐substituted cyclic enones furnishing the corresponding adducts with quaternary stereocenter in excellent enantioselectivities.</p> </abstract>