Olefin‐Directed Palladium‐Catalyzed Regio‐ and Stereoselective Oxidative Arylation of Allenes1. (16th June 2015)

• Record Type: Journal Article
• Authors: Zhu, Can; Yang, Bin; Jiang, Tuo; Bäckvall, Jan‐E.
• Is Part Of: Angewandte Chemie. Volume 127:Number 31(2015)
• Page Start: 9194
• Page End: 9197
• Publication Date: 2015-06-16
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201502924
• Languages: English
• ISSNs: 0044-8249

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>An olefin‐directed palladium‐catalyzed oxidative regio‐ and stereoselective arylation of allenes to afford 1, 3, 6‐trienes has been established. A number of functionalized allenes, including 2, 3‐ and 3, 4‐dienoates and 3, 4‐dienol derivatives, have been investigated and found to undergo the olefin‐directed allene arylation. The olefin moiety has been proven to be a crucial element for the arylating transformation.</p> </abstract>