Catalyst‐Switchable Regiocontrol in the Direct Arylation of Remote CH Groups in Pyrazolo[1, 5‐a]pyrimidines1. Issue 30 (10th June 2015)
- Record Type:
- Journal Article
- Title:
- Catalyst‐Switchable Regiocontrol in the Direct Arylation of Remote CH Groups in Pyrazolo[1, 5‐a]pyrimidines1. Issue 30 (10th June 2015)
- Main Title:
- Catalyst‐Switchable Regiocontrol in the Direct Arylation of Remote CH Groups in Pyrazolo[1, 5‐a]pyrimidines1
- Authors:
- Bedford, Robin B.
Durrant, Steven J.
Montgomery, Michelle - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The regiodivergent palladium‐catalyzed CH arylation of pyrazolo[1, 5‐<italic>a</italic>]pyrimidine has been achieved, wherein the switch in regioselectivity between positions C3 and C7 is under complete catalyst control. A phosphine‐containing palladium catalyst promotes the direct arylation at the most acidic position (C7), whereas a phosphine‐free catalyst targets the most electron‐rich position (C3).</p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 54:Issue 30(2015)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 54:Issue 30(2015)
- Issue Display:
- Volume 54, Issue 30 (2015)
- Year:
- 2015
- Volume:
- 54
- Issue:
- 30
- Issue Sort Value:
- 2015-0054-0030-0000
- Page Start:
- 8787
- Page End:
- 8790
- Publication Date:
- 2015-06-10
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201502150 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3806.xml