Deep eutectic solvents: biorenewable reaction media for Au(i)-catalysed cycloisomerisations and one-pot tandem cycloisomerisation/Diels–Alder reactions1. Issue 7 (6th July 2015)

• Record Type: Journal Article
• Authors: Vidal, C.; Merz, L.; García-Álvarez, J.
• Is Part Of: Green chemistry. Volume 17:Issue 7(2015)
• Page Start: 3870
• Page End: 3878
• Publication Date: 2015-07-06
• Subjects: Environmental chemistry -- Industrial applications -- Periodicals; Environmental management -- Periodicals; 660
• DOI: 10.1039/c5gc00656b
• Languages: English
• ISSNs: 1463-9262

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1xv6k2tq" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Cycloisomerisation reactions of (<italic>Z</italic>)-enynols can be conveniently performed in the eutectic mixture 1<italic>ChCl</italic>/2<italic>Gly</italic> under standard bench experimental conditions by using the novel Au(<sc>i</sc>) complex <bold>3</bold> as catalyst. Furthermore, one-pot tandem cyclosiomerization/Diels–Alder reactions are reported in this eutectic mixture.</p> </abstract>