Synthesis and Lewis acidity of fluorophosphonium cations1. Issue 27 (21st July 2015)

• Record Type: Journal Article
• Authors: Caputo, Christopher B.; Winkelhaus, Daniel; Dobrovetsky, Roman; Hounjet, Lindsay J.; Stephan, Douglas W.
• Is Part Of: Dalton transactions. Volume 44:Issue 27(2015)
• Page Start: 12256
• Page End: 12264
• Publication Date: 2015-07-21
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00217f
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj1xv607r0" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A series of fluorophosphonium salts, [R₃PF][X] (R = alkyl or aryl; X = FB(C₆F₅)₃, [B(C₆F₅)₄]), have been prepared by reactions of phosphine/borane frustrated Lewis pairs (FLPs) with XeF₂ or difluorophosphoranes with [Et₃Si][B(C₆F₅)₄].</p> </abstract>