Charge redistribution and a shortening of the Fe—As bond at the quantum critical point of SmO1–xFxFeAs. (24th June 2015)

• Record Type: Journal Article
• Authors: Cheng, Jie; Dong, Peng; Xu, Wei; Liu, Shengli; Chu, Wangsheng; Chen, Xianhui; Wu, Ziyu
• Is Part Of: Journal of synchrotron radiation. Volume 22:Part 4(2015)
• Page Start: 1030
• Page End: 1034
• Publication Date: 2015-06-24
• Subjects: Synchrotron radiation -- Periodicals; Free electron lasers -- Periodicals; 539.73505
• DOI: 10.1107/S1600577515008450
• Languages: English
• ISSNs: 0909-0495

Abstract

<abstract abstract-type="main" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>Many researchers have pointed out that there is a quantum critical point (QCP) in the F‐doped SmOFeAs system. In this paper, the electronic structure and local structure of the superconductive FeAs layer in SmO_{1–<italic>x</italic>}F_{<italic>x</italic>}FeAs as a function of the F‐doping concentration have been investigated using Fe and As <italic>K</italic>‐edge X‐ray absorption spectroscopy. Experiments performed on the X‐ray absorption near‐edge structure showed that in the vicinity of the QCP the intensity of the pre‐edge feature at the Fe‐edge decreases continuously, while there is a striking rise of the shoulder‐peak at the As edge, suggesting the occurrence of charge redistribution near the QCP. Further analysis on the As <italic>K</italic>‐edge extended X‐ray absorption fine structure demonstrated that the charge redistribution originates mostly from a shortening of the Fe—As bond at the QCP. An evident relationship between the mysterious QCP and the fundamental Fe—As bond was established, providing new insights on the interplay between QCP, charge dynamics and the local structural Fe—As bond in Fe‐based superconductors.</p> </abstract>