An Iodine‐Catalyzed Hofmann–Löffler Reaction1. Issue 28 (28th May 2015)
- Record Type:
- Journal Article
- Title:
- An Iodine‐Catalyzed Hofmann–Löffler Reaction1. Issue 28 (28th May 2015)
- Main Title:
- An Iodine‐Catalyzed Hofmann–Löffler Reaction1
- Authors:
- Martínez, Claudio
Muñiz, Kilian - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Iodine reagents have been identified as economically and ecologically benign alternatives to transition metals, although their application as molecular catalysts in challenging CH oxidation reactions has remained elusive. An attractive iodine oxidation catalysis is now shown to promote the convenient conversion of carbon–hydrogen bonds into carbon–nitrogen bonds with unprecedented complete selectivity. The reaction proceeds by two interlocked catalytic cycles comprising a radical chain reaction, which is initiated by visible light as energy source. This unorthodox synthetic strategy for the direct oxidative amination of alkyl groups has no biosynthetic precedence and provides an efficient and straightforward access to a general class of saturated nitrogenated heterocycles.</p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 54:Issue 28(2015)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 54:Issue 28(2015)
- Issue Display:
- Volume 54, Issue 28 (2015)
- Year:
- 2015
- Volume:
- 54
- Issue:
- 28
- Issue Sort Value:
- 2015-0054-0028-0000
- Page Start:
- 8287
- Page End:
- 8291
- Publication Date:
- 2015-05-28
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201501122 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3059.xml