Inside Back Cover: trans‐(Cl)‐[Ru(5, 5′‐diamide‐2, 2′‐bipyridine)(CO)2Cl2]: Synthesis, Structure, and Photocatalytic CO2 Reduction Activity (Chem. Eur. J. 28/2015). Issue 28 (6th July 2015)

• Record Type: Journal Article
• Authors: Kuramochi, Yusuke; Fukaya, Kyohei; Yoshida, Makoto; Ishida, Hitoshi
• Is Part Of: Chemistry. Volume 21:Issue 28(2015)
• Page Start: 10243
• Page End: 10243
• Publication Date: 2015-07-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201590125
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold> <italic>trans</italic>‐(Cl)‐[Ru(L)(CO)₂Cl₂]‐type complexes</bold> (L: 2, 2′‐bipyridyl derivatives) catalyze CO₂ reduction to produce carbon monoxide and formate with a photosensitizer and an electron donor under irradiation of visible light. Amide groups attached to the complexes at the 5, 5′‐positions in the ligand affect the catalytic activities. A systematic study on the photochemical CO₂ reduction shows the relationship between the CO₂ reduction activities and the reduction potential of the ruthenium complexes. For more details, see the Full Paper by H. Ishida and co‐workers on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 10049 ff.</ext-link><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgj1c48v71m" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></p> </abstract>