<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A new and general, catalyst‐free strategy for the formation of C(sp<sup>3</sup>)—O bonds is established by iodosobenzene diacetate‐mediated oxygenation of benzylic C(sp<sup>3</sup>)—H bonds with N‐hydroxyamides.</p> </abstract>