An Isolable Radical Anion of an Organosilicon Cluster Containing Only σ Bonds1. (26th May 2015)
- Record Type:
- Journal Article
- Title:
- An Isolable Radical Anion of an Organosilicon Cluster Containing Only σ Bonds1. (26th May 2015)
- Main Title:
- An Isolable Radical Anion of an Organosilicon Cluster Containing Only σ Bonds1
- Authors:
- Otsuka, Kyohei
Matsumoto, Naozumi
Ishida, Shintaro
Kyushin, Soichiro - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The radical anion of octa‐<italic>tert</italic>‐butyloctasilacubane was generated and isolated. The EPR spectrum showed the satellites due to the tertiary <sup>13</sup>C nuclei of the eight <italic>tert</italic>‐butyl groups. The X‐ray crystallographic analysis showed that the SiSi bonds are shortened and the SiC bonds are elongated compared with those of octa‐<italic>tert</italic>‐butyloctasilacubane. These results are well explained by the distribution of an unpaired electron in the singly occupied molecular orbital (SOMO).</p> </abstract>
- Is Part Of:
- Angewandte Chemie. Volume 127:Number 27(2015)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 127:Number 27(2015)
- Issue Display:
- Volume 127, Issue 27 (2015)
- Year:
- 2015
- Volume:
- 127
- Issue:
- 27
- Issue Sort Value:
- 2015-0127-0027-0000
- Page Start:
- 7944
- Page End:
- 7947
- Publication Date:
- 2015-05-26
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201500523 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 3258.xml