Solution structural characterization of an array of nanoscale aqueous inorganic Ga13−xInx (0 ≤ x ≤ 6) clusters by 1H-NMR and QM computations1. Issue 7 (15th July 2015)

• Record Type: Journal Article
• Authors: Oliveri, Anna F.; Wills, Lindsay A.; Hazlett, Caitlyn R.; Carnes, Matthew E.; Chang, I-Ya; Ha-Yeon Cheong, Paul; Johnson, Darren W.
• Is Part Of: Chemical science. Volume 6:Issue 7(2015:Jul.)
• Page Start: 4071
• Page End: 4085
• Publication Date: 2015-07-15
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5sc00776c
• Languages: English
• ISSNs: 2041-6520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj148z2fmz" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Complete structural determination by ¹H NMR spectroscopy and QM computations reveals a series of heterometallic Ga_{13−<italic>x</italic>}In_{<italic>x</italic>}(μ₃-OH)₆(μ₂-OH)₁₈(H₂O)₂₄](NO₃)₁₅ clusters persist in solution and can exist as an isomeric mixture.</p> </abstract>