Carbene catalyzed umpolung of α, β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates1. Issue 7 (15th July 2015)

• Record Type: Journal Article
• Authors: Yatham, Veera Reddy; Neudörfl, Jörg-M.; Schlörer, Nils E.; Berkessel, Albrecht
• Is Part Of: Chemical science. Volume 6:Issue 7(2015:Jul.)
• Page Start: 3706
• Page End: 3711
• Publication Date: 2015-07-15
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5sc01027f
• Languages: English
• ISSNs: 2041-6520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj148z2rtx" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />NMR/X-ray evidence is provided for hitherto postulated reactivity patterns of homoenolate <italic>vs.</italic> azolium enolate intermediates in NHC-catalyzed umpolung of enals.</p> </abstract>