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Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands1. Issue 7 (15th July 2015)
Record Type:
Journal Article
Title:
Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands1. Issue 7 (15th July 2015)
Main Title:
Revealing the thermodynamic driving force for ligand-based reductions in quinoids; conceptual rules for designing redox active and non-innocent ligands1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj148z31pb" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The easy reduction of quinoid ligands is driven thermodynamically by superior M–L electrostatics and σ-bonding in the reduced form.</p> </abstract>