Organocatalytic asymmetric chlorinative dearomatization of naphthols1. Issue 7 (15th July 2015)

• Record Type: Journal Article
• Authors: Yin, Qin; Wang, Shou-Guo; Liang, Xiao-Wei; Gao, De-Wei; Zheng, Jun; You, Shu-Li
• Is Part Of: Chemical science. Volume 6:Issue 7(2015:Jul.)
• Page Start: 4179
• Page End: 4183
• Publication Date: 2015-07-15
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5sc00494b
• Languages: English
• ISSNs: 2041-6520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj148z2x8p" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A highly enantioselective chlorinative dearomatization of 1-naphthol and 2-naphthols was realized for the first time, providing chiral naphthalenones with a Cl-containing all-substituted stereocenter in excellent yields and enantioselectivity (up to 97% yield and 96% ee).</p> </abstract>