Synthesis, structure, and spectral and electrochemical properties of chromium(iii) tris-(8-hydroxyquinolinate)1. Issue 25 (7th July 2015)

• Record Type: Journal Article
• Authors: Freitas, Ana R.; Silva, Mónica; Ramos, M. Luísa; Justino, Licínia L. G.; Fonseca, Sofia M.; Barsan, Madalina M.; Brett, Christopher M. A.; Silva, M. Ramos; Burrows, Hugh D.
• Is Part Of: Dalton transactions. Volume 44:Issue 25(2015)
• Page Start: 11491
• Page End: 11503
• Publication Date: 2015-07-07
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00727e
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj146sq9xz" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Having the HOMO of chromium(<sc>iii</sc>) tris-(8-hydroxyquinolinate) mainly on metal 3d orbitals and the LUMO on the ligand leads to increased electrochemical stability.</p> </abstract>