Probing the Catalytic Activity of Reduced Graphene Oxide Decorated with Au Nanoparticles Triggered by Visible Light. Issue 27 (26th May 2015)

• Record Type: Journal Article
• Authors: Wang, Jiale; Trindade, Fabiane J.; de Aquino, Caroline B.; Pieretti, Joana C.; Domingues, Sergio H.; Ando, Romulo A.; Camargo, Pedro H. C.
• Is Part Of: Chemistry. Volume 21:Issue 27(2015)
• Page Start: 9889
• Page End: 9894
• Publication Date: 2015-05-26
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201500677
• Languages: English
• ISSNs: 0947-6539

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Hybrid materials in which reduced graphene oxide (rGO) is decorated with Au nanoparticles (rGO–Au NPs) were obtained by the in situ reduction of GO and AuCl₄⁻_(aq) by ascorbic acid. On laser excitation, rGO could be oxidized as a result of the surface plasmon resonance (SPR) excitation in the Au NPs, which generates activated O₂ through the transfer of SPR‐excited hot electrons to O₂ molecules adsorbed from air. The SPR‐mediated catalytic oxidation of <italic>p</italic>‐aminothiophenol (PATP) to <italic>p</italic>, <italic>p</italic>′‐dimercaptoazobenzene (DMAB) was then employed as a model reaction to probe the effect of rGO as a support for Au NPs on their SPR‐mediated catalytic activities. The increased conversion of PATP to DMAB relative to individual Au NPs indicated that charge‐transfer processes from rGO to Au took place and contributed to improved SPR‐mediated activity. Since the transfer of electrons from Au to adsorbed O₂ molecules is the crucial step for PATP oxidation, in addition to the SPR‐excited hot electrons of Au NPs, the transfer of electrons from rGO to Au contributed to increasing the electron density of Au above the Fermi level and thus the Au‐to‐O₂ charge‐transfer process.</p> </abstract>