ChemInform Abstract: Iridium‐Catalyzed Asymmetric Hydrogenation of 2‐Pyridyl Cyclic Imines: A Highly Enantioselective Approach to Nicotine Derivatives. Issue 27 (18th June 2015)

• Record Type: Journal Article
• Authors: Guo, Cui; Sun, Dong‐Wei; Yang, Shuang; Mao, Shen‐Jie; Xu, Xiao‐Hua; Zhu, Shou‐Fei; Zhou, Qi‐Lin
• Is Part Of: ChemInform. Volume 46:Issue 27(2015)
• Page Start: no
• Page End: no
• Publication Date: 2015-06-18
• Subjects: Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201527143
• Languages: English
• ISSNs: 0931-7597

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A substituent adjacent to the pyridine N atom is crucial to block the coordination ability of the pyridine moiety, an effect which is evidently overturned by the proximate second N atom in substrate (Vb).</p> </abstract>