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ChemInform Abstract: Nucleophile‐Dependent Diastereoselectivity in the Ring Expansion of Pyrimidines to Give 1, 3‐Diazepines. Issue 27 (18th June 2015)
Record Type:
Journal Article
Title:
ChemInform Abstract: Nucleophile‐Dependent Diastereoselectivity in the Ring Expansion of Pyrimidines to Give 1, 3‐Diazepines. Issue 27 (18th June 2015)
Main Title:
ChemInform Abstract: Nucleophile‐Dependent Diastereoselectivity in the Ring Expansion of Pyrimidines to Give 1, 3‐Diazepines.
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The conversion of pyrimidine (I) into 1, 3‐diazepines involves the stereoselective addition of a nucleophile to a bicyclic cyclopropane intermediate to give cis or trans substituted products.</p> </abstract>