Kinetic Investigation Exploiting Local Parameter Subset Selection: Isomerization of 1‐Decene using a Rh‐Biphephos Catalyst. Issue 6 (27th March 2015)

• Record Type: Journal Article
• Authors: Jörke, Andreas; Triemer, Susann; Seidel‐Morgenstern, Andreas; Hamel, Christof; Klemm, Elias; Sauer, Jörg
• Is Part Of: Chemie Ingenieur Technik. Volume 87:Issue 6(2015:Jun.)
• Page Start: 713
• Page End: 725
• Publication Date: 2015-03-27
• Subjects: Chemical engineering -- Patents -- Periodicals; Chemical engineering -- Periodicals; Chemical industry -- Periodicals; Chemistry, Technical -- Periodicals; 660.05
• DOI: 10.1002/cite.201400148
• Languages: English
• ISSNs: 0009-286X

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A kinetic study of the isomerization of 1‐decene using a Rh‐Biphephos catalyst was performed in order to parameterize a mechanistic kinetic model to observed experimental data. For the derivation of the kinetic model, a previously proposed catalytic cycle was revised regarding the catalyst pre‐equilibrium including the formation of inactive or non‐selective Rh‐species. In order to estimate the model parameters and to support model reduction, a method based on parameter subset selection was extended and applied. Using this approach, sensitive kinetic parameters were identified and determined for the reduced kinetic model.</p> </abstract>