Iridium‐Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides1. Issue 26 (12th May 2015)
- Record Type:
- Journal Article
- Title:
- Iridium‐Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides1. Issue 26 (12th May 2015)
- Main Title:
- Iridium‐Catalyzed Enantioselective Allylic Alkylation with Functionalized Organozinc Bromides1
- Authors:
- Hamilton, James Y.
Sarlah, David
Carreira, Erick M. - Abstract:
- <abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>Iridium‐catalyzed enantioselective allylic alkylation of branched racemic carbonates with functionalized alkylzinc bromide reagents is described. Enabled by a chiral Ir/(P, olefin) complex, the method described allows allylic substitution with various primary and secondary alkyl nucleophiles with excellent regio‐ and enantioselectivities. The developed reaction was showcased in a concise, asymmetric synthesis of (−)‐preclamol.</p> </abstract>
- Is Part Of:
- Angewandte Chemie international edition. Volume 54:Issue 26(2015)
- Journal:
- Angewandte Chemie international edition
- Issue:
- Volume 54:Issue 26(2015)
- Issue Display:
- Volume 54, Issue 26 (2015)
- Year:
- 2015
- Volume:
- 54
- Issue:
- 26
- Issue Sort Value:
- 2015-0054-0026-0000
- Page Start:
- 7644
- Page End:
- 7647
- Publication Date:
- 2015-05-12
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/journal/10.1002/(ISSN)1521-3773 ↗
http://www.interscience.wiley.com/jpages/1433-7851 ↗
http://onlinelibrary.wiley.com/ ↗ - DOI:
- 10.1002/anie.201501851 ↗
- Languages:
- English
- ISSNs:
- 1433-7851
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000500
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 3216.xml