Large and negative magnetic anisotropy in pentacoordinate mononuclear Ni(ii) Schiff base complexes1. Issue 20 (28th May 2015)

• Record Type: Journal Article
• Authors: Nemec, Ivan; Herchel, Radovan; Svoboda, Ingrid; Boča, Roman; Trávníček, Zdeněk
• Is Part Of: Dalton transactions. Volume 44:Issue 20(2015)
• Page Start: 9551
• Page End: 9560
• Publication Date: 2015-05-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00600g
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj101b5nwf" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Pentacoordinate Ni(<sc>ii</sc>) complexes with pentadentate Schiff base ligands possess large and negative values of axial magnetic anisotropy. The relationship between the shape of the coordination polyhedron and uniaxial anisotropy is outlined.</p> </abstract>