New donor–acceptor conjugates based on a trifluorenylporphyrin linked to a redox–switchable ruthenium unit12. Issue 20 (28th May 2015)

• Record Type: Journal Article
• Authors: Merhi, Areej; Zhang, Xu; Yao, Dandan; Drouet, Samuel; Mongin, Olivier; Paul, Frédéric; Williams, J. A. Gareth; Fox, Mark A.; Paul-Roth, Christine O.
• Is Part Of: Dalton transactions. Volume 44:Issue 20(2015)
• Page Start: 9470
• Page End: 9485
• Publication Date: 2015-05-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c5dt00348b
• Languages: English
• ISSNs: 1477-9226

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj101b5c3m" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Spectroelectrochemical studies show four accessible redox states on dyad <bold>3</bold> with the first oxidation process taking place at the Ru(<sc>ii</sc>) centre and the second oxidation and first reduction processes at the porphyrin centre.</p> </abstract>