Heterometal‐Embedded Organic Conjugate Frameworks from Alternating Monomeric Iron and Cobalt Metalloporphyrins and Their Application in Design of Porous Carbon Catalysts. (27th April 2015)

• Record Type: Journal Article
• Authors: Lin, Qipu; Bu, Xianhui; Kong, Aiguo; Mao, Chengyu; Bu, Fei; Feng, Pingyun
• Is Part Of: Advanced materials. Volume 27:Number 22(2015)
• Page Start: 3431
• Page End: 3436
• Publication Date: 2015-04-27
• Subjects: Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adma.201500727
• Languages: English
• ISSNs: 0935-9648

Abstract

<abstract abstract-type="graphical" xml:lang="en" id="adma201500727-abs-0001"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <bold>The use of an alternately conjugated networking method</bold> to prepare the first porous heterometalloporphyrinic frameworks with ordered alternation of Fe and Co moieties is presented. Subsequent carbonization gives an Fe and Co co‐embedded porous carbon composite with a very high activity and remarkable electrochemical stability for oxygen reduction reaction in both alkaline and acidic electrolytes. <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjrk4h242" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></p> </abstract>