Titanium carbenoid-mediated cyclopropanation of allylic alcohols: selectivity and mechanism1. Issue 22 (14th June 2015)

• Record Type: Journal Article
• Authors: Durán-Peña, M. J.; Botubol-Ares, J. M.; Hanson, J. R.; Hernández-Galán, R.; Collado, I. G.
• Is Part Of: Organic & biomolecular chemistry. Volume 13:Issue 22(2015)
• Page Start: 6325
• Page End: 6332
• Publication Date: 2015-06-14
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c5ob00544b
• Languages: English
• ISSNs: 1477-0520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjqwj29mw" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A new method for the chemo- and stereoselective conversion of allylic alcohols into the corresponding cyclopropane derivatives has been developed using a titanium carbenoid. The scope, limitations and mechanism are discussed.</p> </abstract>