A mechanistic investigation of anti-elimination in (Z)-1, 2-bis(arylseleno)-1-alkenes and their sulfur analogs1. Issue 21 (7th June 2015)

• Record Type: Journal Article
• Authors: Tarao, Asami; Tabuchi, Yukako; Sugimoto, Eri; Ikeda, Miki; Uchimoto, Hitomi; Arimitsu, Kenji; Kimura, Hiroyuki; Kawasaki, Ikuo; Kawahata, Masatoshi; Yamaguchi, Kentaro; Nishide, Kiyoharu
• Is Part Of: Organic & biomolecular chemistry. Volume 13:Issue 21(2015)
• Page Start: 5964
• Page End: 5971
• Publication Date: 2015-06-07
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c5ob00490j
• Languages: English
• ISSNs: 1477-0520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjp059bdn" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Selenoxide <italic>anti</italic>-elimination in (<italic>Z</italic>)-1, 2-bis(arylseleninyl)-1-alkenes is induced by the Se⋯O interaction, whereas the sulfur analogs lacks this type of nonbonding interaction.</p> </abstract>