A novel transition metal free [bis-(trifluoroacetoxy)iodo]benzene (PIFA) mediated oxidative ipso nitration of organoboronic acids1. Issue 17 (7th May 2015)

• Record Type: Journal Article
• Authors: Chatterjee, Nachiketa; Bhatt, Divya; Goswami, Avijit
• Is Part Of: Organic & biomolecular chemistry. Volume 13:Issue 17(2015)
• Page Start: 4828
• Page End: 4832
• Publication Date: 2015-05-07
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c5ob00337g
• Languages: English
• ISSNs: 1477-0520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjn2npgjs" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A mild, convenient and transition metal free methodology for oxidative <italic>ipso</italic> nitration of organoboronic acids, including heteroaryl- and alkylboronic acids, has been developed using a combination of [bis-(trifluoroacetoxy)]iodobenzene (PIFA) – <italic>N</italic>-bromosuccinimide (NBS) and sodium nitrite as the nitro source.</p> </abstract>