Boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides with silylborane and an alkoxy base: expanded scope and mechanistic studies1. Issue 5 (20th May 2015) - Yamamoto, Eiji
Abstract A transition-metal-free method has been developed for the boryl substitution of functionalized aryl-, heteroaryl- and alkenyl halides using a silylborane/alkoxy-base reagent. Borylation of (Z)-alkenyl halides proceeded in a stereoretentive manner.