"Armed and disarmed" theory in the addition of an azide radical to glucals1. Issue 48 (28th May 2015)

• Record Type: Journal Article
• Authors: Wang, Wenjun; Yang, Zhongyue; Xu, Yun; Liu, Taibao; Song, Tianbang; Zhao, Yunyan; Xu, Xiufang; Zhao, Wei; Wang, Peng George
• Is Part Of: RSC advances. Volume 5:Issue 48(2015)
• Page Start: 38577
• Page End: 38580
• Publication Date: 2015-05-28
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c5ra00296f
• Languages: English
• ISSNs: 2046-2069

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjn2mhtvm" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />"Armed" glucals were prone to undergo kinetic process. The torsional strains govern the selectivity. Meanwhile, "disarmed" glucals preferred thermodynamic radical addition. A sialic acid containing trisaccharide was also synthesized by the method.</p> </abstract>