Direct aerobic liquid phase epoxidation of propylene catalyzed by Mn(iii) porphyrin under mild conditions: evidence for the existence of both peroxide and Mn(iv)-oxo species from in situ characterizations1. Issue 38 (30th April 2015)

• Record Type: Journal Article
• Authors: Li, Yang; Zhou, Xiantai; Chen, Shaoyun; Luo, Rongchang; Jiang, Jun; Liang, Zhongxiu; Ji, Hongbing
• Is Part Of: RSC advances. Volume 5:Issue 38(2015)
• Page Start: 30014
• Page End: 30020
• Publication Date: 2015-04-30
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c4ra15601c
• Languages: English
• ISSNs: 2046-2069

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjn2f8hrh" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />Manganese(<sc>iii</sc>) porphyrin exhibited excellent activity for the selective oxidation of propylene. Experimental evidences that the generation of peroxide and Mn(<sc>iv</sc>) oxo species, which was well confirmed by <italic>in situ</italic> IR, <italic>in situ</italic> UV and MS.</p> </abstract>