A charge-disproportionate ordered state with δ = 0.75 in a chemically sensitive donor/acceptor Dδ+2A2δ− layered framework1. Issue 37 (7th May 2015)

• Record Type: Journal Article
• Authors: Fukunaga, Hiroki; Yoshino, Takafumi; Sagayama, Hajime; Yamaura, Jun-ichi; Arima, Taka-hisa; Kosaka, Wataru; Miyasaka, Hitoshi
• Is Part Of: Chemical communications. Volume 51:Issue 37(2015)
• Page Start: 7795
• Page End: 7798
• Publication Date: 2015-05-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc01633a
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjn27qn0d" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A novel charge-disproportionation state with <italic>δ</italic> = 0.75 was observed in an electron-donor (D)/-acceptor (A) D^{<italic>δ</italic>+}₂A^{2<italic>δ</italic>−} layered framework by chemically tuning the electron-donating affinity of D.</p> </abstract>