Inside Cover: Reversible 1, 1‐Hydroboration: Boryl Insertion into a CN Bond and Competitive Elimination of HBR2 or RH (Angew. Chem. Int. Ed. 18/2015). Issue 18 (8th April 2015)

• Record Type: Journal Article
• Authors: Yang, Deng‐Tao; Mellerup, Soren K.; Wang, Xiang; Lu, Jia‐Sheng; Wang, Suning
• Is Part Of: Angewandte Chemie international edition. Volume 54:Issue 18(2015)
• Page Start: 5264
• Page End: 5264
• Publication Date: 2015-04-08
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.201502753
• Languages: English
• ISSNs: 1433-7851

Abstract

<abstract abstract-type="graphical" xml:lang="en"> <title> <x xml:space="preserve">Abstract</x> </title> <p>N‐heterocyclic molecules undergo an unprecedented 1, 1‐hydroboration with a variety of boranes (HBR₂) to form new BN heterocycles that undergo two competitive thermal‐elimination pathways: retro‐1, 1‐hydroboration or RH elimination. As S. Wang et al. show in their Communication on <ext-link ext-link-type="doi" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">page 5498 ff., </ext-link> the elimination pathway is an efficient method for providing highly emissive BN‐doped arenes. The cover art was designed and painted by Yufei Li, a Ph.D. student at Queen′s University.<boxed-text content-type="graphic" position="anchor" orientation="portrait"><graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjjm90qqp" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /></boxed-text></p> </abstract>