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Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts1. (4th February 2015)
Record Type:
Journal Article
Title:
Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts1. (4th February 2015)
Main Title:
Cooperative Catalysis: Enantioselective Propargylic Alkylation of Propargylic Alcohols with Enecarbamates Using Ruthenium/Phosphoramide Hybrid Catalysts1
<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>The diastereo‐ and enantioselective propargylic alkylation of propargylic alcohols with <italic>E</italic>‐enecarbamates in the presence of a catalytic amount of thiolate‐bridged diruthenium complexes bearing an optically active phosphoramide moiety gives the corresponding propargylic alkylated products (up to 97 % <italic>ee</italic>).</p> </abstract>