N‐methyliminodiacetic acid as a simple and highly efficient ligand for palladium‐catalyzed Suzuki–Miyaura cross‐coupling of aryl chlorides. (3rd February 2015)

• Record Type: Journal Article
• Authors: Qi, Liang; Zhou, Xiuling; Li, Xiaogang; Li, Wei; Lv, Meiyun; Guo, Mengping
• Is Part Of: Applied organometallic chemistry. Volume 29:Number 4(2015:Apr.)
• Page Start: 244
• Page End: 246
• Publication Date: 2015-02-03
• Subjects: Organometallic chemistry -- Periodicals; Organometallic compounds -- Periodicals; 547.05
• DOI: 10.1002/aoc.3279
• Languages: English
• ISSNs: 0268-2605

Abstract

<abstract abstract-type="main"> <title> <x xml:space="preserve">Abstract</x> </title> <p>A simple, air‐stable, inexpensive and easily prepared molecule, <italic>N</italic>‐methyliminodiacetic acid (MIDA), is reported as a ligand for palladium‐catalyzed <named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">Suzuki–Miyaura</named-content><named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">cross‐coupling reaction</named-content> of phenylboronic acid with aryl chlorides. The yield of the corresponding Suzuki <named-content content-type="reactionType" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink">coupling reaction</named-content> is up to around 90% at both high temperature of 80°C and room temperature under ambient atmosphere. Copyright © 2015 John Wiley &amp; Sons, Ltd.</p> </abstract>