Intriguing differences in hydrogen adsorption in CPO-27 materials induced by metal substitution1. Issue 9 (7th March 2015)

• Record Type: Journal Article
• Authors: Rosnes, Mali H.; Opitz, Martin; Frontzek, Matthias; Lohstroh, Wiebke; Embs, Jan Peter; Georgiev, Peter A.; Dietzel, Pascal D. C.
• Is Part Of: Journal of materials chemistry. Volume 3:Issue 9(2015)
• Page Start: 4827
• Page End: 4839
• Publication Date: 2015-03-07
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c4ta05794e
• Languages: English
• ISSNs: 2050-7488

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj412gzb5" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />We present a comparative study of hydrogen gas adsorption experiments on CPO-27–Cu and –Mn. The initial isosteric heat of adsorption in CPO-27–Cu is low for a material containing open metal sites and in contrast to the other members of the CPO-27 series, including the Mn compound.</p> </abstract>