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An X-ray absorption spectroscopy investigation of the coordination environment of electrogenerated Ni(ii)-pseudohalide complexes arising from the anodic polarization of Ni electrodes in DMSO solutions of NCO−, NCS− and NCSe− ions1. Issue 20 (6th March 2015)
Record Type:
Journal Article
Title:
An X-ray absorption spectroscopy investigation of the coordination environment of electrogenerated Ni(ii)-pseudohalide complexes arising from the anodic polarization of Ni electrodes in DMSO solutions of NCO−, NCS− and NCSe− ions1. Issue 20 (6th March 2015)
Main Title:
An X-ray absorption spectroscopy investigation of the coordination environment of electrogenerated Ni(ii)-pseudohalide complexes arising from the anodic polarization of Ni electrodes in DMSO solutions of NCO−, NCS− and NCSe− ions1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgh3xs43xbt" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />EXAFS/XANES measurements combined with IR spectroelectrochemistry directly probe <italic>in situ</italic> the coordination sphere of electrogenerated ions in metal electrode systems so obviating the need to isolate ions unchanged from the electrolyte for analysis.</p> </abstract>