Copper‐Catalyzed Direct Arylselenation of Anilines by CH Bond Cleavage. Issue 5 (25th February 2015)

• Record Type: Journal Article
• Authors: Ricordi, Vanessa G.; Thurow, Samuel; Penteado, Filipe; Schumacher, Ricardo F.; Perin, Gelson; Lenardão, Eder J.; Alves, Diego
• Is Part Of: Advanced synthesis & catalysis. Volume 357:Issue 5(2015)
• Page Start: 933
• Page End: 939
• Publication Date: 2015-02-25
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201400804
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>We describe here an efficient and regioselective synthesis of arylselanyl anilines by copper‐catalyzed direct arylselenation of arylamines. Using a catalytic amount of copper iodide in dimethyl sulfoxide at 110 °C under an air atmosphere, a range of arylselanyl anilines was obtained directly from substituted diaryl diselenides in moderate to good yields via CH bond cleavage of aryl amines.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjbsh6nkn" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>