Acid‐Catalyzed Synthesis of α, β‐Disubstituted Conjugated Enones by a Meyer–Schuster‐Type Rearrangement in Allenols. Issue 5 (12th March 2015)

• Record Type: Journal Article
• Authors: Alcaide, Benito; Almendros, Pedro; Cembellín, Sara; Martínez del Campo, Teresa
• Is Part Of: Advanced synthesis & catalysis. Volume 357:Issue 5(2015)
• Page Start: 1070
• Page End: 1078
• Publication Date: 2015-03-12
• Subjects: Catalysis -- Periodicals; Organic compounds -- Synthesis -- Periodicals; Chemistry -- Periodicals; Chemistry, Technical -- Periodicals; Chemistry -- Periodicals; Catalysis -- Periodicals; Technology, Pharmaceutical -- Periodicals; 547.2
• DOI: 10.1002/adsc.201400928
• Languages: English
• ISSNs: 1615-4150

Abstract

<abstract abstract-type="main" xml:lang="en"> <title>Abstract</title> <p>A novel, direct and simple methodology to gain access to α, β‐disubstituted conjugated enones from α‐allenols in a sustainable metal catalysis context, considering the inexpensiveness and environmentally friendliness of iron(III) species and protons, has been developed.</p> <p> <boxed-text content-type="graphic" position="anchor" orientation="portrait"> <graphic position="anchor" mimetype="image" xlink:href="ark:/27927/pgjbsh6f5j" orientation="portrait" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> </boxed-text> </p> </abstract>