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An efficient approach to gem-difluorocyclopropylstannanes via highly regio- and stereoselective hydrostannylation of gem-difluorocyclopropenes and their unique ring-opening reaction to afford β-fluoroallylic alcohols1. Issue 12 (28th March 2015)
Record Type:
Journal Article
Title:
An efficient approach to gem-difluorocyclopropylstannanes via highly regio- and stereoselective hydrostannylation of gem-difluorocyclopropenes and their unique ring-opening reaction to afford β-fluoroallylic alcohols1. Issue 12 (28th March 2015)
Main Title:
An efficient approach to gem-difluorocyclopropylstannanes via highly regio- and stereoselective hydrostannylation of gem-difluorocyclopropenes and their unique ring-opening reaction to afford β-fluoroallylic alcohols1
<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjbfz9wq1" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" /> <italic>gem</italic>-Difluorocyclopropylstannanes, prepared <italic>via</italic> the hydrostannylation of <italic>gem</italic>-difluorocyclopropenes, were treated with MeLi and then quenching agents, to give (<italic>Z</italic>)-β-fluoroallyllic alcohols, ethers, esters, and amides.</p> </abstract>