Isotope effect profiles in the N-demethylation of N, N-dimethylanilines: a key to determine the pKa of nonheme Fe(iii)–OH complexes1. Issue 24 (25th March 2015)

• Record Type: Journal Article
• Authors: Barbieri, Alessia; De Gennaro, Martina; Di Stefano, Stefano; Lanzalunga, Osvaldo; Lapi, Andrea; Mazzonna, Marco; Olivo, Giorgio; Ticconi, Barbara
• Is Part Of: Chemical communications. Volume 51:Issue 24(2015)
• Page Start: 5032
• Page End: 5035
• Publication Date: 2015-03-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc00411j
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjbf9x4vp" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />p<italic>K</italic>_a of [(N4Py)Fe^III–OH]²⁺ is obtained from the kinetic isotope effect profiles in the <italic>N</italic>-demethylation of <italic>N</italic>, <italic>N</italic>-dimethylanilines promoted by [(N4Py)Fe^IVO]²⁺.</p> </abstract>