A homochiral magnet based on D3 symmetric [(NaO3)Co3] clusters: from spontaneous resolution to absolute chiral induction1. Issue 24 (25th March 2015)

• Record Type: Journal Article
• Authors: Yao, Ru-Xin; Cui, Xin; Wang, Jun; Zhang, Xian-Ming
• Is Part Of: Chemical communications. Volume 51:Issue 24(2015)
• Page Start: 5108
• Page End: 5111
• Publication Date: 2015-03-25
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c5cc00003c
• Languages: English
• ISSNs: 1359-7345

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgjbfb1sxn" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />A pair novel 3D chiral magnets have been synthesized using the achiral ligand imidazole-4-acrylate <italic>via</italic> spontaneous resolution, in which the <italic>D</italic>₃ symmetric chiral [(NaO₆)Co₃] clusters act as nodes. By using chiral induction agent, they are driven to controllable homochiral crystals.</p> </abstract>