Solvent- and phase-controlled photochirogenesis. Enantiodifferentiating photoisomerization of (Z)-cyclooctene sensitized by cyclic nigerosylnigerose-based nanosponges crosslinked by pyromellitate1. Issue 10 (14th March 2015)

• Record Type: Journal Article
• Authors: Wei, Xueqin; Liang, Wenting; Wu, Wanhua; Yang, Cheng; Trotta, Francesco; Caldera, Fabrizio; Mele, Andrea; Nishimoto, Tomoyuki; Inoue, Yoshihisa
• Is Part Of: Organic & biomolecular chemistry. Volume 13:Issue 10(2015)
• Page Start: 2905
• Page End: 2912
• Publication Date: 2015-03-14
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c4ob02390k
• Languages: English
• ISSNs: 1477-0520

Abstract

<abstract abstract-type="toc"> <title> <x xml:space="preserve">Abstract</x> </title> <p> <graphic position="anchor" id="ga" xlink:href="ark:/27927/pgj40zvp30" xlink:type="simple" xmlns:xlink="http://www.w3.org/1999/xlink" />The enantioselectivity of the (<italic>E</italic>)-cyclooctene produced critically depended on the solvent and also on the phase evolved, maximizing at the flowing/rigid gel border.</p> </abstract>